川北某黑色页岩型铼矿工艺矿物学研究

通过矿相显微镜、扫描电镜、电子探针、X射线能谱元素面分析等多种手段综合研究了川北某黑色页岩型铼矿中铼的赋存状态。样品为黑色页岩,有机碳含量较高。粘土矿物总量为14.6%,黄铁矿含量16.2%,石英含量37.7%。样品具典型的粘土结构,矿物粒度微细。铼有两种赋存状态,一种呈类质同象形式赋存于黄铁矿内,另一种则以分散形式存在。典型黄铁矿测点Re平均含量为0.024%。黄铁矿是Re的重要载体矿物。建议通过浮选分离黄铁矿,从而实现Re的富集。      

回转窑煅烧段烟气最高温度的间接测量

通过对球团回转窑内的热平衡分析,得到回转窑稳定工作时,煅烧段烟气最高温度与窑尾烟气温度之间的理论关系式。该公式表明回转窑在稳定工作时,窑尾烟气温度与煅烧段烟气最高温度存在线性关系。通过三维建模,运用有限元技术对窑尾烟气温度与煅烧段烟气最高温度进行了数值模拟。研究结果可为回转窑煅烧段温度在线监测和自动化调节火焰温度提供理论指导。     

浅析混凝土搅拌站的防雷

近年来,我市因雷击而导致搅拌站系统瘫痪停产、影响工程进度的事件时有发生,在针对混凝土搅拌站配料秤的实际检定工作中,也常发现配料秤的称重传感器因雷击损坏而影响计量准确性。因此,对混凝土搅拌站防雷的研究具有重要意义。本文阐述了雷电对混凝土搅拌站的主要危害,分析了混凝土搅拌站常见的雷击原因及其防护措施,旨在引起生产方、安装方以及使用方对混凝土搅拌站防雷的共同重视。     

磷酸高效分解磷矿实验研究

为改进湿法磷酸生产工艺,提高副产石膏的品质,减少湿法磷酸固体副产物磷石膏堆存产生的经济和环保压力,进行了磷酸分解磷矿制磷酸的实验研究。采用贵州某磷矿为主要原料,研究了湿法磷酸预分解磷矿的反应条件。通过单因素实验确定了湿法磷酸分解磷矿最优反应条件：反应温度为75 ℃,磷酸与磷矿的质量比（液固比）为9,反应时间为3 h,磷酸质量分数为30%（以五氧化二磷计）。在此条件下,磷矿的分解率为98.62%。     

Control of the particle microstructure during the synthesis of bulk-polymerized transparent methacrylate-acrylonitrile-butadiene-styrene resin

A series of methacrylate-acrylonitrile-butadiene-styrene (MABS) resins was prepared using bulk polymerization. The polarity of the continuous phase and the compatibility of two phases were changed by adjusting the methyl methacrylate (MMA) content, choosing values that were close to styrene-butadiene rubber solubility value. The possibility of controlling the microstructure of the MABS resin by changing the polarity of the components and the compatibility of two phases was assessed. The dynamic mechanical analysis shows that the compatibility of two phases varies with the MMA content. The morphological analysis shows that increasing MMA contents results in a gradual decrease in the sub-inclusion structure with a network skeleton of rubber particles, and that all the particles become solid rubber when the MMA content reaches 75%. The sub-inclusion structure reappears but does not have a network skeleton when the MMA content is 90%. The impact strength and morphological analysis indicate that the solid rubber particles and the sub-inclusion structure with a network skeleton provide excellent toughness, while the sub-inclusion structure without a network skeleton does not. In contrast, the transmittance of the ABS resin first increased and then decreased with increasing MMA content.     

南水北调中线工程受水区二期需调水量预测研究

2002年12月国务院批复了《南水北调工程总体规划》，明确中线工程分两期建设。目前，一期工程已经通水。近年来，随着社会经济的快速发展，受水区的人口、生产规模、节水水平、人们对环境的要求都发生了变化，因此有必要根据新的情况对受水区的用水需求重新预测。分析了城市化发展和城镇用水变化的新形势，依据流域、区域水资源规划成果，提出了中线二期工程受水区需调水量，并与《南水北调中线工程规划》提出的二期需调水量进行对比，以供各方参考。     

Magnetic Resonance Signal Amplification by Reversible Exchange of Selective PyFALGEA Oligopeptide Ligands Towards Epidermal Growth Factor Receptors

The biorelevant PyFALGEA oligopeptide ligand, which is selective towards the epidermal growth factor receptor (EGFR), has been successfully employed as a substrate in magnetic resonance signal amplification by reversible exchange (SABRE) experiments. It is demonstrated that PyFALGEA and the iridium catalyst IMes form a PyFALGEA:IMes molecular complex. The interaction between PyFALGEA:IMes and H₂ results in a ternary SABRE complex. Selective 1D EXSY experiments reveal that this complex is labile, which is an essential condition for successful hyperpolarization by SABRE. Polarization transfer from parahydrogen to PyFALGEA is observed leading to significant enhancement of the ¹H NMR signals of PyFALGEA. Different iridium catalysts and peptides are inspected to discuss the influence of their molecular structures on the efficiency of hyperpolarization. It is observed that PyFALGEA oligopeptide hyperpolarization is more efficient when an iridium catalyst with a sterically less demanding NHC ligand system such as IMesBn is employed. Experiments with shorter analogues of PyFALGEA, that is, PyLGEA and PyEA, show that the bulky phenylalanine from the PyFALGEA oligopeptide causes steric hindrance in the SABRE complex, which hampers hyperpolarization with IMes. Finally, a single-scan ¹H NMR SABRE experiment of PyFALGEA with IMesBn revealed a unique pattern of NMR lines in the hydride region, which can be treated as a fingerprint of this important oligopeptide.     

Sensor network design based on system-wide reliability criteria. Part I: Objectives

Reliability based criteria are quite popular for optimal sensor network design. We present a modified definition of system reliability for sensor network design for two applications: reliable estimation of variables in a steady state linear flow process, and reliable fault detection and diagnosis for any process. Unlike the weakest-link based definition of system reliability in the literature, the proposed definition considers the entire system and is consistent with the reliability concept used in classical reliability literature. For each application, dual approaches for defining system reliability are proposed, and their analogy with the reliability problem in the classical reliability literature is established. Using examples and stochastic simulations, the advantage of using the proposed system reliability in contrast to the existing definition is illustrated. Part II of this series of articles presents methods for efficient generation of the system reliability function and its use in optimization-based approaches for designing optimal sensor networks.